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Proton Cranes ─ Tautomeric Systems for Intramolecular Cargo Delivery
Nature effectively employs the light-induced transfer of a proton for rapid interconversion between different electronic [...]
Tautomerism in 1-Pyridin-2-yl-1H-pyrazol-5-ols through the Prism of Molecular Switching: The Rare Case of OH/CH Switching upon Acidic Input
The tautomeric behavior of 1-(2-pyridinyl)-1H-pyrazol-5-ols has been investigated in solution using UV–vis and NMR spectroscopies [...]
Reversible Switching Based on Truly Intramolecular Long-Range Proton Transfer─Turning the Theoretical Concept into Experimental Reality
Herein, we demonstrate a working prototype of a conjugated proton crane, a reversible tautomeric switching [...]