Proton Cranes ─ Tautomeric Systems for Intramolecular Cargo Delivery

Nature effectively employs the light-induced transfer of a proton for rapid interconversion between different electronic states of a molecule and uses tautomerism as a functional design principle in biological systems. Twenty-five years ago, the theoretical design concept of proton cranes was introduced to describe molecules capable of transferring protons at a long-range upon photoexcitation, by […]

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